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Labeling & Marking System

Page Updated January 2008

Manufacturer's Responsibility

Name and Address
Identity of Hazardous Components
Appropriate Hazard Warnings

User's Responsibility

Identity of Hazardous Components
Appropriate Hazard Warnings
CAS# -- Chemical Abstract Service Number
Assure that Manufacturer's label is not defaced or removed

OSU's HMLS* LABELING SYSTEM
*(Hazardous Materials Labeling System)

CODE ORIENTED
EASY TO LEARN
COMPLEMENTS MANUFACTURER'S LABELING

Here is the list of OSU's PPE symbols

hazcom label

Note:NOTE: 
A * next to the Health number means that the substance has chronic health effects.

HEALTH
4
Deadly: even the slightest exposure to this substance would be life threatening. Only specialized protective clothing, for these materials, should be worn.
3
Extreme Danger: serious injury would result from exposure to this substance. Do not expose any body surface to these materials. Full protective measures should be taken.
2
Dangerous: exposure to this substance would be hazardous to health. Protective measures are indicated.
1
Slight Hazard: irritation or minor injury would result from exposure to this substance. Protective measures are indicated.
0
No Hazard: exposure to this substance offers no significant risk to health.

FLAMMABILITY
4
Flash Point Below 73ºF and Boiling Point Below 100ºF: this substance is very flammable, volatile or explosive depending on its state. Extreme caution should be used in handling or storing of these materials.
3
Flash Point Below 100ºF: flammable, volatile or explosive under almost all normal temperature conditions. Exercise great caution in storage or handling of these materials.
2
Flash Point Below 200ºF: moderately heated conditions may ignite this substance. Caution procedures should be employed in handling.
1
Flash Point Above 200ºF: this substance must be preheated to ignite. Most combustible solids would be in this category.
0
Will Not Burn: substances that will not burn.

REACTIVITY
4
May Detonate: substances that are readily capable of detonation or explosion at normal temperatures and pressures. Evacuate area if exposed to heat or fire.
3
Explosive: substances that are readily capable of detonation or explosion by a strong initiating source, such as heat, shock or water. Monitor from behind explosion-resistant barriers.
2
Unstable: violent chemical changes are possible at normal or elevated temperatures and pressures. Potentially violent or explosive reaction may occur when mixed with water. Monitor from a safe distance.
1
Normally stable: substances that may become unstable at elevated temperatures and pressures or when mixed with water. Approach with caution.
0
Stable: substances which will remain stable when exposed to heat, pressure or water.

example of a placardSIGNS AND PLACARDS

All buildings on Oklahoma State University property will be placarded in compliance with the law. Each building which contains over the TPQ (threshold planning quantity) of a hazardous substance will bear the appropriately numbered, diamond-shaped placard approved by the National Fire Protection Association (NFPA).

(See example of placard at right)


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